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Actually, Acrylics are polymers. They are just a different type. Acrylics are already crosslinked (other polymers crosslink when they mix with the air) that's why they tend to be a little more difficult to apply and wipe off. (eg. Klasse) They also tend to sheet water more than bead.
Acrylics are not better than polymers. It's like saying what's better a Buick or a Cadillac? What is better? And for what purpose? There is no answer.
You can apply a carnauba over anything. They have a more difficult time adhereing to some polymers vs acrylics due to the slickness of the polymer surface. You can apply an acrylic over a polymer, but it will degrade it since acrylics are high in solvents and have abrasives in them. (They require it to give them bite to bond to surfaces) You can apply a polymer over an acrylic as well.
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